Spectral parameters for the nu(6) region of HCOOH and its measurement in the infrared tropospheric spectrum

Citation
A. Perrin et al., Spectral parameters for the nu(6) region of HCOOH and its measurement in the infrared tropospheric spectrum, J GEO RES-A, 104(D15), 1999, pp. 18661-18666
Citations number
26
Categorie Soggetti
Earth Sciences
Volume
104
Issue
D15
Year of publication
1999
Pages
18661 - 18666
Database
ISI
SICI code
Abstract
New spectral parameters (line positions and intensities) have been generate d for the nu(6) band of HCOOH, which agree well with 0.002 cm(-1) resolutio n infrared laboratory spectra. The line positions were derived from previou sly published spectroscopic constants [Bumgarner et al., 1988]. New relativ e intensities were derived from the analysis of A type and B type transitio ns. The new line parameters allow improved quantitative analysis of atmosph eric spectra from the 1105 cm(-1) Q branch, provided that the previously ne glected HDO strong tropospheric absorption in this region is taken into acc ount.