A. Perrin et al., Spectral parameters for the nu(6) region of HCOOH and its measurement in the infrared tropospheric spectrum, J GEO RES-A, 104(D15), 1999, pp. 18661-18666
New spectral parameters (line positions and intensities) have been generate
d for the nu(6) band of HCOOH, which agree well with 0.002 cm(-1) resolutio
n infrared laboratory spectra. The line positions were derived from previou
sly published spectroscopic constants [Bumgarner et al., 1988]. New relativ
e intensities were derived from the analysis of A type and B type transitio
ns. The new line parameters allow improved quantitative analysis of atmosph
eric spectra from the 1105 cm(-1) Q branch, provided that the previously ne
glected HDO strong tropospheric absorption in this region is taken into acc
ount.