Validation of Global Ozone Monitoring Experiment cloud fractions relevant for accurate ozone column retrieval

The Global Ozone Monitoring Experiment (GOME), launched on board the ERS-2 satellite of the European Space Agency, is a spectrometer measuring the Ear th's reflectivity between 240 and 790 nm. The main geophysical product of G OME is the ozone vertical column density, also called ozone column. For acc urate ozone column retrievals the presence of clouds should be taken into a ccount. Therefore, as part of the operational ozone column retrieval algori thm, cloud fraction is derived by the initial cloud fitting; algorithm (ICF A) from the spectral reflectivity between 758 and 778 nm, which encloses th e O-2 A band. In ICFA, cloud top pressure is assumed a priori, and is taken from the International Satellite Cloud Climatology Project (ISCCP) databas e. We validated the ICFA (version 2.3) cloud fraction product in two ways. First, a statistical approach was performed comparing monthly average ICFA cloud fractions with monthly average cloud fractions from ISCCP. Global clo ud patterns ill monthly average ICFA cloud fraction maps compare reasonably well with those from ISCCP. Second, a detailed comparison for individual p ixels was performed between ICFA cloud fractions and cloud fractions derive d from collocated Along Track Scanning Radiometer-2 (ATSR-2) data. We found that large differences exist between the (effective) cloud fractions from ATSR-2 and ICFA. The mean difference between the cloud fractions of ATSR-2 and ICFA is 0.18; the standard deviation of the difference is 0.23. It is a rgued that the errors in the ICFA cloud fractions are probably due to error s in the assumed cloud top pressure. A modified version of ICFA, which is l ess sensitive to the assumed, cloud top pressure, is presented. This yields a much improved agreement with the ATSR-2 cloud fractions. Effects of erro rs in cloud fraction and cloud top height on the vertical ozone column dens ity retrieved from GOME are discussed.