TEM analysis of tweed structure in high-palladium dental alloys

Citation
Sv. Nitta et al., TEM analysis of tweed structure in high-palladium dental alloys, J MAT S-M M, 10(9), 1999, pp. 513-517
Citations number
19
Categorie Soggetti
Multidisciplinary
Journal title
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE
ISSN journal
09574530 → ACNP
Volume
10
Issue
9
Year of publication
1999
Pages
513 - 517
Database
ISI
SICI code
0957-4530(199909)10:9<513:TAOTSI>2.0.ZU;2-R
Abstract
Transmission electron microscopy and convergent-beam electron diffraction w ere used to study three high-palladium dental alloys: an as-cast Pd-Ga allo y, a cast Pd-Cu-Ga alloy aged at room temperature for over 5 years, and a c ast Pd-Cu-Ga alloy annealed at 1023 K for 2 h and slowly cooled to room tem perature. Bands containing a tweed structure in the Pd-Ga alloy were 120 de grees twins with (1 (1) over bar 0) mirror planes. Within these bands the a lloy had a face-centered tetragonal structure with a c/a ratio of 1.03. The aged Pd-Cu-Ga alloy contained a larger amount of tweed structure than the original as-cast alloy, along with randomly oriented bands and thin lath-li ke regions. The annealed Pd-Cu-Ga alloy contained rectangular particles of a secondary phase that may be Pd2Ga, Pd5Ga2 or Pd13Ga5. The microtwinned ba nd structure relieves the strain energy arising from transformation of the f.c.c. palladium solid solution on cooling. (C) 1999 Kluwer Academic Publis hers.