InXn atomization energies are computed for n = 1-3 and X = H, Cl, and CH3.
The geometries and frequencies are determined using density functional theo
ry. The atomization energies are computed at the coupled cluster level of t
heory. The complete basis set limit is obtained by extrapolation. The scala
r relativistic effect is computed using the Douglas-Kroll approach. While t
he heats of formation for InH, InCl, and InCl3 are in good agreement with e
xperiment, the current results show that the experimental value for In(CH3)
(3) must be wrong.