Synthesis and structures of neutral and cationic 1-azaallyl-aluminium methyls

Authors
Bourget, L Hitchcock, PB Lappert, MF
Citation
L. Bourget et al., Synthesis and structures of neutral and cationic 1-azaallyl-aluminium methyls, J CHEM S DA, (16), 1999, pp. 2645-2646
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
16
Year of publication
1999
Pages
2645 - 2646
Database
ISI
SICI code
0300-9246(1999):16<2645:SASONA>2.0.ZU;2-H
Abstract
The 1-azaallylaluminium compounds [Al{N( R)C(Bu-t)C(H) R}{N(R)C(Bu-t)=C(H)R }Me] (X-ray characterised), Al{N(R)C(Bu-t)C(H)R}Me-2, Al{N(R)C(Ph)=C(H)R}Me -2 3 and Al{N(R)C(Ph)=C(H)R}(2)Me(thf) were obtained from the appropriate m ethylaluminium chloride and 1-azaallyllithium; 3 with B(C6F5)(3) gave [Al{N (R)C(Ph)=C(H)R}Me(thf)(OEt2)][BMe(C6F5)(3)] (R = SiMe3).