An octanuclear pyromellitimidato(2-) palladium complex: coordinative assembly of a molecular box

Citation
Hm. Colquhoun et al., An octanuclear pyromellitimidato(2-) palladium complex: coordinative assembly of a molecular box, J CHEM S DA, (16), 1999, pp. 2651-2652
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
16
Year of publication
1999
Pages
2651 - 2652
Database
ISI
SICI code
0300-9246(1999):16<2651:AOPPCC>2.0.ZU;2-#
Abstract
Reaction of pyromellitimide with the binuclear palladium complex [Pd-2(mu-C l-2)(1,2-C6H4NMe2)(2)] in the presence of base affords a box-like, pyromell itimidato(2-), octa-palladium complex exhibiting helical chirality, for whi ch H-1 NMR and single crystal X-ray data are reported.