Preparation and crystal structures of oxoosmium(VI) diolato complexes

Authors
Lehtonen, A Jokela, J Edwards, PG Sillanpaa, R
Citation
A. Lehtonen et al., Preparation and crystal structures of oxoosmium(VI) diolato complexes, J CHEM S DA, (16), 1999, pp. 2785-2788
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
16
Year of publication
1999
Pages
2785 - 2788
Database
ISI
SICI code
0300-9246(1999):16<2785:PACSOO>2.0.ZU;2-5
Abstract
Reaction of OsO4 with one equivalent of PPh3 in the presence of the tertiar y diols, 2,3-dimethyl-2,3-butanediol (H(2)pin) and 1,1'-bicyclohexane-1,1'- diol (H(2)bicy), afforded the new oxoosmium(VI) complexes [OsO(diol)(2)]. T he molecular structures of [OsO(pin)(2)], [OsO(bicy)(2)] and its adduct [Os O(bicy)(2)]. H(2)bicy . PPh3O were determined by X-ray crystallography.