Anode materials for a hydrogen sulfide solid oxide fuel cell

Citation
C. Yates et J. Winnick, Anode materials for a hydrogen sulfide solid oxide fuel cell, J ELCHEM SO, 146(8), 1999, pp. 2841-2844
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics","Material Science & Engineering
Journal title
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
ISSN journal
00134651 → ACNP
Volume
146
Issue
8
Year of publication
1999
Pages
2841 - 2844
Database
ISI
SICI code
0013-4651(199908)146:8<2841:AMFAHS>2.0.ZU;2-1
Abstract
The performance of a solid oxide fuel cell utilizing hydrogen sulfide as a fuel was studied with CoS1.035, WS2, and Li2S/CoS1.035 anode materials. The electrolyte was yttria-stabilized zirconia with a thickness ranging from 4 0-500 mu m. Power densities of over 400 mW/cm(2) were obtained with the Li/ Co sulfide based material and gas analysis demonstrated hydrogen sulfide de struction levels in excess of 75%. Cell performance was noted to degrade sl ightly over time, which can be attributed to air leaks within the experimen tal system or delamination of the electrodes. (C) 1999 The Electrochemical Society. S0013-4651(98)12-026-6. All nights reserved.