We use a plan-view transmission electron microscope technique to unambiguou
sly image the "physical" interface position between Si and furnace grown Si
O2 layers. The effect of postoxidation annealing on the interface roughness
of Si/SiO2 was studied with this technique. While no obvious effect due to
postoxidation annealing on roughness was observed for silicon (111) a post
oxidation annealing at 900 degrees C dramatically removed roughness at Si(1
00)/SiO2 interfaces. A model was developed to explain our experimental resu
lts based on the idea of kinetic smoothening and oxidation induced rougheni
ng. Qualitative agreement has been reached. (C) 1999 The Electrochemical So
ciety. S0013-4651(98)05-046-0. All rights reserved.