Chemical potential for simple fluids from equations of state

Citation
A. Mulero et al., Chemical potential for simple fluids from equations of state, MOLEC PHYS, 97(3), 1999, pp. 453-462
Citations number
41
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
97
Issue
3
Year of publication
1999
Pages
453 - 462
Database
ISI
SICI code
0026-8976(19990810)97:3<453:CPFSFF>2.0.ZU;2-Z
Abstract
The chemical potential for both the hard-sphere and the Lennard-Jones syste ms is calculated from analytical equations of state proposed in the literat ure and results are compared with data obtained by different authors from c omputer simulations. Eighteen equations of state for hard spheres, some of them recently published, were considered, and for the Lennard-Jones system three semi-empirical equations and two semi-theoretical ones, one of the la tter being proposed by us in a previous work. Good agreement, except for pa rticular expressions and/or particular temperature or density ranges, is fo und for most cases and for both hard-sphere and Lennard-Jones fluids. Our r esults indicate that the use of expressions which are more complex than the Carnahan-Stariing equation for hard spheres up than our proposal For Lenna rd-Jones fluids is not needed to obtain the chemical potential accurately.