Jbp. Soares et al., A NOVEL SOLUTION OF SAITOS INTEGRAL-EQUATION FOR RANDOM SCISSION - APPLICATION ON THE VISBREAKING OF ISOTACTIC POLYPROPYLENE, Polymer reaction engineering, 5(1-2), 1997, pp. 25-44
A novel solution of Saito's integral equation for random scission of p
olymer chains having a broad distribution of molecular weights has bee
n developed. This solution is in agreement with standard numerical sol
utions of Saito's integral equation and is also in agreement with the
experimental data for visbreaking of isotactic polypropylene, confirmi
ng that the visbreaking of isotactic polypropylene does indeed involve
random scission with no long chain branching or crosslinking.