We obtain within the orthogonalized plane wave approximation surface-plasmo
n mediated neutralization rates for hydrogenic ions and for several metalli
c surfaces. The effects of the electronic density and of the work function
of the surfaces are analyzed. The collective neutralization rates increase
with density while the slope of the exponential curve for the rates increas
es when the work function decreases. For charged (Z) hydrogenic ions we fou
nd that these collective transitions are allowed only for states with n = Z
.