X-ray band spectra from laser produced highly ionized hafnium plasmas have
been observed in the 4.6-5.0 Angstrom range. The contributions from electro
n-impact excitation and dielectronic recombination in this region are studi
ed in detail using a quasi-relativistic configuration interaction method. I
t is found that the spectral structure due to electron-impact excitations i
s almost the same as in dielectronic recombination. The calculated spectra
of 3d-5f transitions of the Ni-Ge ionization states can explain the observe
d features of the band spectra in this region very well.