H-1 NMR study of distribution of functional groups in carboxymethyl dextran

Authors
Sokolov, VB Krasnov, KA Matyushichev, IY Passet, BV
Citation
Vb. Sokolov et al., H-1 NMR study of distribution of functional groups in carboxymethyl dextran, RUS J AP CH, 72(4), 1999, pp. 701-703
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
72
Issue
4
Year of publication
1999
Pages
701 - 703
Database
ISI
SICI code
1070-4272(199904)72:4<701:HNSODO>2.0.ZU;2-8
Abstract
The distribution of functional groups in a monomeric unit of carboxymethyl dextran was studied by H-1 NMR. The distribution of carboxymethyl groups be tween the 2-, 3-, and 4-positions of the glucopyranose unit of dextran was studied as a function of the total degree of substitution. The activity con stants were determined for hydroxyls in 2-, 3-, and 4-positions of the unit in carboxymethylation reaction.