Highly diastereoselective synthesis of (6-methylenepyrrolo[1,2-c]oxazol-7-yl)- methylphosphonate by an application of radical reaction

Authors
Yuasa, Y Fujimaki, N Yokomatsu, T Ando, J Shibuya, S
Citation
Y. Yuasa et al., Highly diastereoselective synthesis of (6-methylenepyrrolo[1,2-c]oxazol-7-yl)- methylphosphonate by an application of radical reaction, SYN COMMUN, 29(20), 1999, pp. 3573-3580
Citations number
10
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
20
Year of publication
1999
Pages
3573 - 3580
Database
ISI
SICI code
0039-7911(1999)29:20<3573:HDSO(>2.0.ZU;2-H
Abstract
Highly diastereoselective synthesis of (6-methylenepyrrolo[1,2-c]oxazol-7-y l)methylphosphonate 5 was achieved by an application of intramolecular radi cal cyclization of vinyl radical to beta-carbon of unsaturated phosphonate.