Preparation, crystal structure and characterization of C-60 center dot 2[(Ph3P)AuCl]

Authors
Graja, A Waplak, S Gritsenko, VV Spitsina, NG Drichko, NV
Citation
A. Graja et al., Preparation, crystal structure and characterization of C-60 center dot 2[(Ph3P)AuCl], SYNTH METAL, 106(1), 1999, pp. 29-34
Citations number
27
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
106
Issue
1
Year of publication
1999
Pages
29 - 34
Database
ISI
SICI code
0379-6779(19990930)106:1<29:PCSACO>2.0.ZU;2-Y
Abstract
Investigations of crystal structure, infrared spectra and electron spin res onance of the complex of the fullerene C-60 with chloro(triphenylophosphine )gold have been performed. It was stated that the C-60. 2[(Ph3P)AuCl] compl ex is a molecular crystal in which van der Waals interactions are predomina nt. The electron spin resonance (ESR) spectrum was discussed and explained. A phase transition at about 195-200 K was suggested. (C) 1999 Elsevier Sci ence S.A. All rights reserved.