AN EFFECTIVE SYNTHESIS OF 1,3-OXATHIOLANES

Citation
L. Streinz et al., AN EFFECTIVE SYNTHESIS OF 1,3-OXATHIOLANES, Collection of Czechoslovak Chemical Communications, 62(4), 1997, pp. 665-671
Citations number
25
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
62
Issue
4
Year of publication
1997
Pages
665 - 671
Database
ISI
SICI code
0010-0765(1997)62:4<665:AESO1>2.0.ZU;2-B
Abstract
2-Alkyl- or 2,2-dialkyl-1,3-oxathiolanes can be effectively prepared f rom aldehydes or ketones and 2-mercaptoethanol, with triisopropylsilyl triflate as a catalyst. The reaction is over within minutes and, desp ite the fact that water is nor removed during the reaction, the yields of products are high.