{4,4 '-dimethyl-6,6 '-bis(morpholino-methyl)-2,2 '-[1,3-propanediylbis(nitrilo methylidene)]diphenolato-O,N,N ',O ')-manganese(II) diperchlorate monohydrate

Authors
Thiruimurugan, R Raj, SSS Shanmugam, G Fun, HK Manonmani, J Kandaswamy, M
Citation
R. Thiruimurugan et al., {4,4 '-dimethyl-6,6 '-bis(morpholino-methyl)-2,2 '-[1,3-propanediylbis(nitrilo methylidene)]diphenolato-O,N,N ',O ')-manganese(II) diperchlorate monohydrate, ACT CRYST C, 55, 1999, pp. 1218-1220
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
8
Pages
1218 - 1220
Database
ISI
SICI code
0108-2701(19990815)55:<1218:{'''>2.0.ZU;2-U
Abstract
In the title compound, [Mn(C28H36N4O4)](ClO4)(2). H2O, the morpholine rings adopt chair conformations. The geometry around the Mn-II ion is slightly d istorted square planar. The dihedral angle between the N/Mn/N and O/Mn/O pl anes is 10.1 (1)degrees. In addition to van der Waals interactions, the mol ecules are stabilized by N-H ... O and C-H ... O hydrogen bonds.