Bis(1,3-dibutylimidazolidin-2-one-O)bis-(nitrato-O,O ')dioxouranium(VI)

Citation
Zb. Cao et al., Bis(1,3-dibutylimidazolidin-2-one-O)bis-(nitrato-O,O ')dioxouranium(VI), ACT CRYST C, 55, 1999, pp. 1270-1272
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
8
Pages
1270 - 1272
Database
ISI
SICI code
0108-2701(19990815)55:<1270:B'>2.0.ZU;2-9
Abstract
In the title complex, [UO2(NO3)(2)(C11H22N2O)(2)] the central UO22+ cation is centrosymmetrically coordinated by six further O atoms, of which two an from the carbonyl groups of the 1,3-dibutylimidazolidin-2-one ligands and f our from the two nitrate anions, forming a distorted hexagonal bipyramidd T he average carbonyl U-O bond length is 2.345 (3) Angstrom, which is the sho rtest value among similar dinitratodioxouranium complexes.