Three Pt-II catecholate and 1,2-dithiocatecholate complexes

Authors
Lesley, MJG Clegg, W Marder, TB Norman, NC Orpen, AG Scott, AJ Starbuck, J
Citation
Mjg. Lesley et al., Three Pt-II catecholate and 1,2-dithiocatecholate complexes, ACT CRYST C, 55, 1999, pp. 1272-1275
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
8
Pages
1272 - 1275
Database
ISI
SICI code
0108-2701(19990815)55:<1272:TPCA1C>2.0.ZU;2-K
Abstract
In the crystal structures of the three title complexes, (benzene-1,2-diolat o-O,O')bis( triphenylphosphine)platinum(II), [Pt(C6H3O2)(C18H15P)(2)], (1), (benzene-1,2-dithiolato-S,S')bis( triphenylphosphine)platinum(II), [Pt(C6H 4S2)(C18H15P)(2)], (2), and the n-hexane hemisolvate of (benzene-1,2-diolat o-O,O')bis(tricyclohexylphosphine)platinum(II), [Pt(C6H4O2)(C18H33P)(2)]. 0 .5C(6)H(14), (3), the Pt atoms are tetracoordinate with distorted square-pl anar geometry. Compounds (1) and (2) are isostructural.