Aqua[4-(4-chlorophenyl)-2-phenylthiazole-5-acetato-O]trimethyltin(IV)

Authors
Parvez, M Ali, S Mazhar, M Bhatti, MH Khokhar, MN
Citation
M. Parvez et al., Aqua[4-(4-chlorophenyl)-2-phenylthiazole-5-acetato-O]trimethyltin(IV), ACT CRYST C, 55, 1999, pp. 1280-1282
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
8
Pages
1280 - 1282
Database
ISI
SICI code
0108-2701(19990815)55:<1280:A>2.0.ZU;2-A
Abstract
The crystal structure of the title compound, [Sn(CH3)(3)(C17H11ClNO2S)(H2O) ], contains hydrogen-bonded infinite planes, wherein each trimethyltin moie ty is coordinated to a water molecule and an O atom of the carboxylate liga nd. The Sn atom has a distorted trigonal-bipyramidal geometry with three me thyl groups in the equatorial plane [mean Sn-C 2.114(7) Angstrom]. The O at oms bonded to the Sn atom in the axial positions have significantly differe nt Sn-O bond lengths [2.167(4) and 2.490 (4) Angstrom].