2-(p-toluoyl)benzoic acid

Authors
Citation
A. Degen et M. Bolte, 2-(p-toluoyl)benzoic acid, ACT CRYST C, 55, 1999, pp. 1306-1308
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
8
Pages
1306 - 1308
Database
ISI
SICI code
0108-2701(19990815)55:<1306:2A>2.0.ZU;2-2
Abstract
The title compound, C15H12O3, crystallizes as a centrosymmetric dimer hydro gen bonded via the carboxylic acid groups. The carboxylic acid group is nea rly coplanar with the adjacent aromatic ring, which is almost perpendicular to the tolyl ring. In contrast to all comparable o-benzoylbenzoic acid str uctures retrieved from the Cambridge Structural Database, the torsion angle between the carbonyl group linking both aromatic rings and the phenyl ring carrying the carboxylic acid group is less than 90 degrees, resulting in a shorter distance between the two carbonyl O atoms.