The title compound, C15H12O3, crystallizes as a centrosymmetric dimer hydro
gen bonded via the carboxylic acid groups. The carboxylic acid group is nea
rly coplanar with the adjacent aromatic ring, which is almost perpendicular
to the tolyl ring. In contrast to all comparable o-benzoylbenzoic acid str
uctures retrieved from the Cambridge Structural Database, the torsion angle
between the carbonyl group linking both aromatic rings and the phenyl ring
carrying the carboxylic acid group is less than 90 degrees, resulting in a
shorter distance between the two carbonyl O atoms.