(1S,2S,5S,6S)-5,6-dihydroxy-6-methylcyclo-hex-3-en-1,2-diyl diacetate

Citation
S. Russi et al., (1S,2S,5S,6S)-5,6-dihydroxy-6-methylcyclo-hex-3-en-1,2-diyl diacetate, ACT CRYST C, 55, 1999, pp. 1347-1349
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
8
Pages
1347 - 1349
Database
ISI
SICI code
0108-2701(19990815)55:<1347:(D>2.0.ZU;2-K
Abstract
The title compound, C11H16O6, has been synthesized and isolated as the majo r product of the osmylation of (5S,6R)-5,6-diacetoxy-1-methyl-1,3-cyclohexa diene. The molecule crystallizes in the monoclinic space group P2(1). The h exene ring exhibits a puckered distorted half-chair conformation, with all the chiral centres (C3, C4, C5 and C6) in the S configuration. One intramol ecular and two intermolecular hydrogen bonds stabilize the molecule by the formation of infinite chains along b.