Communication: High yields of nanocrystals at ambient temperature have been
attained for several inorganic salts such as ZnS and CuO. The authors repo
rt one-step, solid-state reactions between easily obtained starting materia
ls such as CuCl2. 2H(2)O and NaOH to give nanoparticles with narrow size di
stribution. The process is carried out in air and requires no complex appar
atus, reagents, or techniques and thus it shows potential for mass producti
on of nanocrystals. All of the reactions investigated involve hydrated salt
s, and the role of the water in the reaction mechanism is discussed.