This paper is a contribution to the understanding of the topoclimatic and e
nvironmental geography of the basin where Santiago - one of the most pollut
ed Latin American city - is located. In the first part, land-use change is
analysed looking at the climatic transformation caused by the rapid transit
from natural semiarid surface to urban areas. In the second part, seasonal
weather and daily cycles of slope winds and the available ventilation are
described trying to relate those patterns with the spatial distribution of
air pollution. A combination of meteorological, geographical and cultural f
actors explain extreme air pollution events: meteorologically, Santiago is
under permanent subsidence inversion layers. Geographically, the city is lo
cated in a closed basin surrounded by mountains. Culturally, the urban area
has the highest population concentration (40% of the national total), indu
stries (near 70% of the total) and vehicles, which are the main sources of
smog. The urban and suburban transport system is based on a large number of
buses (diesel) and private cars, both experiencing a rapid growth from the
past few years. The city and specially the transport system generates high
emissions of pollutant, bur the natural semiarid deforested soils and slop
es are also important sources. The local wind system can explain the differ
ential spatial distribution on the concentration of air pollutants in the c
ity and its periphery. In winter train season concentrations of particulate
matter are higher at the centre and the SW part of the city. The andean pi
edmont area (E part of the city) shows minimum values, suggesting major ven
tilation effects of slope and valley winds. Ozone exceeds air quality stand
ards in summer (dry season) at all sites in the centre and periphery. Howev
er, the O-3-concentrations are higher on preferred residential areas locate
d at the piedmont area (E part of the city), suggesting air pollution trans
port effects. Currently, there is no consideration of these local climatic
features in the process of urban planning. (C) 1999 Elsevier Science Ltd. A
ll rights reserved.