The synthesis of sulfur-containing spiro orthocarbonates

Authors
Bromley, MK Gason, SJ Looney, MG Solomon, DH
Citation
Mk. Bromley et al., The synthesis of sulfur-containing spiro orthocarbonates, AUST J CHEM, 52(7), 1999, pp. 657-661
Citations number
16
Categorie Soggetti
Chemistry
Journal title
AUSTRALIAN JOURNAL OF CHEMISTRY
ISSN journal
00049425 → ACNP
Volume
52
Issue
7
Year of publication
1999
Pages
657 - 661
Database
ISI
SICI code
0004-9425(1999)52:7<657:TSOSSO>2.0.ZU;2-I
Abstract
New sulfur-containing spiro orthocarbonates (SOCs) were prepared by using d ichlorodiphenoxymethane. Mercapto alcohols were employed to yield O,S SOCs, and O,S diphenoxy intermediates in a one-step procedure. By adopting a two -step synthesis under basic conditions, a range of sulfur-containing hetero atom SOCs was produced. Preliminary studies indicate that this methodology is applicable to different ring sizes.