Lanthanide organometallic chemistry based on the porphyrinogen skeleton: acetylene and ethylene bridging praseodymium and neodymium eta(5):eta(1):eta(5):eta(1)-bonded to meso-octaethylporphyrinogen

Authors
Campazzi, E Solari, E Scopelliti, R Floriani, C
Citation
E. Campazzi et al., Lanthanide organometallic chemistry based on the porphyrinogen skeleton: acetylene and ethylene bridging praseodymium and neodymium eta(5):eta(1):eta(5):eta(1)-bonded to meso-octaethylporphyrinogen, CHEM COMMUN, (17), 1999, pp. 1617-1618
Citations number
42
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
17
Year of publication
1999
Pages
1617 - 1618
Database
ISI
SICI code
1359-7345(19990907):17<1617:LOCBOT>2.0.ZU;2-M
Abstract
The reaction of meso-octaethylporphyrinogen-lanthanide complexes, [{(eta(5) :eta(1):eta(5):eta(1)-Et8N4)M}Na(thf)(2)] [M = Pr, Nd], with NaC10H8 in an ethylene or acetylene atmosphere leads to the isolation of dimeric species, where the metals are bridged by the [C2H4](2-) and [C-2](2-) anions.