Equilibrium textures in main-chain liquid crystalline polymers

Citation
F. Elias et al., Equilibrium textures in main-chain liquid crystalline polymers, EUROPH LETT, 47(4), 1999, pp. 442-448
Citations number
22
Categorie Soggetti
Physics
Journal title
EUROPHYSICS LETTERS
ISSN journal
02955075 → ACNP
Volume
47
Issue
4
Year of publication
1999
Pages
442 - 448
Database
ISI
SICI code
0295-5075(199908)47:4<442:ETIMLC>2.0.ZU;2-U
Abstract
We analyse the Schlieren textures formed by the nematic director in a therm otropic main-chain liquid crystalline polymer. After an initial coarsening, the textures reach a stable time-independent state which appears to bf an equilibrium function of temperature and material parameters, with a charact eristic length scale xi of order 2 mu m. In particular, we study the evolut ion of this domain size when the temperature approaches the nematic-isotrop ic transition T-ni. The texture size xi increases towards T-ni, but decreas es reversibly when the temperature decreases back into the nematic phase. W e discuss possible theoretical models that may explain such an equilibrium polydomain state of nematic director and the dependence of its size on the nematic order parameter.