Mechanical attrition as a method to produce nanocrystalline (nc) mater
ials is reviewed. its advantages include the fact that all classes of
materials-including brittle compounds-are amenable to the method; it c
an be easily scaled up to tonnage quantities. The phenomenology and su
ggested mechanisms for formation of nc microstructures are discussed f
or ball milling of single component powders, mechanical alloying of mu
lticomponent powders, and mechanical crystallization of amorphous allo
ys. The phenomenology is well documented but microscopic mechanisms aw
ait better understanding of the nature of deformation processes in nc
materials. The problems of contamination and powder consolidation are
briefly considered. (C) 1997 Acta Metallurgica Inc.