DYNAMICAL MAXWELL-GARNETT OPTICAL MODELING OF NANOGOLD POROUS ALUMINACOMPOSITES - MIE AND KAPPA-INFLUENCE ON ABSORPTION MAXIMA

Composites consisting of nanogold in porous alumina host membranes hav e been fabricated and characterized. Nanocluster size (11 nm to 60 nm radius) and shape (prolate to oblate) were varied experimentally. Two phenomena were responsible for the position of maximum absorption (lam bda(max)) of the composites. First, light scattering due to extrinsic electrodynamic effects became important as particle size was increased . This resulted in red shifts in lambda max and is known as the Mie ef fect. Secondly, blue shifts were induced as particle aspect ratio was increased. We have designated shifts due to particle shape and orienta tion as the ''kappa'' effect. The two appeared to exert their influenc e independently. Simulations by means of the dynamical Maxwell-Garnett (DMG) expression resulted in good correlation with experimental lambd a(max). We demonstrate again the versatility of the template method of synthesizing nanostructured materials. (C) 1997 Acta Metallurgica Inc .