Asymmetric epoxidation of 1,2-dihydronaphthalene catalyzed by manganese chiroporphyrins: Stereoinduction directed by steric exclusion

Authors
Perollier, C Pecaut, J Ramasseul, R Marchon, JC
Citation
C. Perollier et al., Asymmetric epoxidation of 1,2-dihydronaphthalene catalyzed by manganese chiroporphyrins: Stereoinduction directed by steric exclusion, INORG CHEM, 38(17), 1999, pp. 3758
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
17
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990823)38:17<3758:AEO1CB>2.0.ZU;2-K
Abstract
High levels of stereoinduction are obtained in the epoxidation of 1,2-dihyd ronaphthalene catalyzed by sterically crowded manganese chiroporphyrin cata lysts, and asymmetric induction is correlated to the degree of nonplanar di stortion of the porphyrin free base in solution.