Novel heterometallic lanthanide silsesquioxane

Authors
Annand, J Aspinall, HC Steiner, A
Citation
J. Annand et al., Novel heterometallic lanthanide silsesquioxane, INORG CHEM, 38(17), 1999, pp. 3941
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
17
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990823)38:17<3941:NHLS>2.0.ZU;2-A
Abstract
A new type of heterometallic silsesquioxane is reported in which Ln (Ln = Y b or Y) is coordinated to one (C6H11)(7)Si7O123- ligandandone(C6H11)(7)Si7O 11(OSiMe3)(2-) ligand. Two Li atoms are incorporated into the structure, on e bonded to two siloxy O atoms and the other to one siloxy O atom, one fram ework O atom, and one OSiMe3 O atom.