Reaction of [Pd2Cl2(mu-dppm)(2)] with arenesulfonyl azides. Kinetics and mechanism of formation of arenesulfonylimido-bridged A-frame adducts

Authors
Foch, I Besenyei, G Simandi, LI
Citation
I. Foch et al., Reaction of [Pd2Cl2(mu-dppm)(2)] with arenesulfonyl azides. Kinetics and mechanism of formation of arenesulfonylimido-bridged A-frame adducts, INORG CHEM, 38(17), 1999, pp. 3944
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
17
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990823)38:17<3944:RO[WAA>2.0.ZU;2-P
Abstract
Substituted arenesulfonyl azides react with [Pd2Cl2(mu-dppm)(2)] in an entr opy-controlled electrophilic process, affording an imido-bridged A-frame ad duct via N-2 extrusion. The Hammett relationship is valid for the 4-substit uents.