Effect of pH in an aqueous medium on the surface area, pore size distribution, density, and porosity of montmorillonite

Surface area, pore volume distribution, and porosity of montmorillonite are determined after being exposed to aqueous solutions with various pH values . For measurement, after each pH treatment the clay samples were freeze-dri ed in order to keep the structure of the clay same as that in the aqueous s olution. Surface area and pore size distribution measurements were performe d on an unmodified and four pH (2.5, 4.0, 5.5, 9.0)-adjusted clay samples u sing N-2 and CO2 as adsorbates. The surface area measurements at lower pH a re lower than those measured at higher pH due to the replacement of Na+ ion s from interlayers at lower pH which may be followed by the reduction of re pulsive forces. As the pH of the montmorillonite increases to 9.0, the surf ace area increases almost seven times compared to that at pH 2.5. Pore size distribution was determined by CO2 adsorption at 273 K for micropores (<20 Angstrom), by N-2 adsorption at 77 K for mesopores (between 20 and 500 Ang strom), and by using both Hg intrusion and N-2 adsorption for macropores (> 500 Angstrom). Since N-2 molecules undergo a molecular sieving at 77 K CO2 gas at 273 K was used to measure the micropore surface area and gave higher surface area measurements than those measured by N-2. Surface area values measured by CO2 adsorption ranged between 30 and 200 m(2)/g for montmorillo nite while those measured by N-2 adsorption were 13.7-70 m(2)/g in the pH r ange studied. (C) 1999 Academic Press.