M. Melnik et al., Copper(II) coordination compounds: Classification and analysis of crystallographic and structural data IV. Trimeric and oligomeric compounds, J COORD CH, 48(3), 1999, pp. 271-374
This review summarizes data for over two hundred and thirty trimeric and ol
igomeric copper(II) coordination compounds. Included are trimeric (73), tet
rameric (135), pentameric (5), hexameric (12), octameric (5), nonameric (2)
and even dodecameric (1) derivatives. In most complexes, the copper(II) is
four-, five- and six-coordinate. The structures are discussed in terms of
the coordination about the copper(II) atoms, and correlation's are drawn be
tween donor atom, bond length and interbond angles. There are several examp
les of distortion isomerism.