Several infrared transitions of the v(s), band of C2H2 perturbed by Xe near
700 cm(-1) have been recorded using a tunable diode-laser spectrometer, eq
uipped with a thermostatically regulated cell. The pressure and temperature
regimes covered during the experiments are respectively ranging between 7,
20 and 200 mbar and 170 and 350 K. The experimental profiles are accurately
studied with a recently proposed lineshape model accounting for the collis
ional confinement narrowing of the Doppler spectral contribution, the inhom
ogeneous collisional broadening and shifting, and the exchange between the
various speed classes of the Maxwell-Boltzmann distribution. The speed depe
ndence of the collisional broadening is either ab initio calculated from a
semiempirical potential or deduced from the experimental temperature depend
ence of the line broadening. It is shown that, for the considered range of
temperature, this speed dependence does not significantly modify the linesh
ape, so that the usual hard and soft models conveniently account for most o
f the observed effects. (C) 1999 Academic Press.