Reactions at solid-liquid interfaces: contrasting chemistry at different crystal faces in the hydroxide-induced reactive dissolution of p-chloranil as revealed by channel flow cell voltammetry

Authors
Hill, E Lloyd-Williams, RR Compton, RG Atherton, JH
Citation
E. Hill et al., Reactions at solid-liquid interfaces: contrasting chemistry at different crystal faces in the hydroxide-induced reactive dissolution of p-chloranil as revealed by channel flow cell voltammetry, J SOL ST EL, 3(6), 1999, pp. 327-330
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
ISSN journal
14328488 → ACNP
Volume
3
Issue
6
Year of publication
1999
Pages
327 - 330
Database
ISI
SICI code
1432-8488(199908)3:6<327:RASICC>2.0.ZU;2-P
Abstract
The (100), (010) and (001) faces of monoclinic crystals of the organic soli d p-chloranil display contrasting reactivities towards hydrolytic dissoluti on induced by aqueous hydroxide ions. The differing behaviour is rationalis ed in terms of the functional groups exposed in the different faces.