Calculation of gas chromatographic retention indices of organic compounds from the boiling points of their structural analogs
Citation
Ig. Zenkevich, Calculation of gas chromatographic retention indices of organic compounds from the boiling points of their structural analogs, J STRUCT CH, 40(1), 1999, pp. 101-107
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
SICI code
0022-4766(199901/02)40:1<101:COGCRI>2.0.ZU;2-K
Abstract
The possibility of calculating gas chromatographic retention indices (I) is
discussed. The indices are important parameters for chromatospectral ident
ification of organic compounds from the boiling points of their structural
analogs (T-b*) using the linear logarithmic equation log I = a log Tb* + bA
+ c, where A are the structural parameters reflecting the one-re-one posit
ion of the compounds being compared ill the corresponding taxonomic groups,
including homologous series.