Calculation of gas chromatographic retention indices of organic compounds from the boiling points of their structural analogs

Authors
Citation
Ig. Zenkevich, Calculation of gas chromatographic retention indices of organic compounds from the boiling points of their structural analogs, J STRUCT CH, 40(1), 1999, pp. 101-107
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
40
Issue
1
Year of publication
1999
Pages
101 - 107
Database
ISI
SICI code
0022-4766(199901/02)40:1<101:COGCRI>2.0.ZU;2-K
Abstract
The possibility of calculating gas chromatographic retention indices (I) is discussed. The indices are important parameters for chromatospectral ident ification of organic compounds from the boiling points of their structural analogs (T-b*) using the linear logarithmic equation log I = a log Tb* + bA + c, where A are the structural parameters reflecting the one-re-one posit ion of the compounds being compared ill the corresponding taxonomic groups, including homologous series.