Citation
Lc. Song et al., Formation and reactions of novel types of bridging sulfido anions, (mu-RE)(mu-S-)[Fe-2(CO)(6)](2)(mu(4)-S) (E = S, Se): Synthesis and structures of double- and triple-butterfly Fe/E cluster complexes, ORGANOMETAL, 18(17), 1999, pp. 3258-3260
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333
→ ACNP
Volume
18
Issue
17
Year of publication
1999
Pages
3258 - 3260
Database
ISI
SICI code
0276-7333(19990816)18:17<3258:FARONT>2.0.ZU;2-C
Abstract
The[Et3NH](+) salts of novel anions (mu RE)- (mu-S-)[Fe2(CO)(6)](2)(mu(4)-S
) (RE = t-BuS, p-MeC6H4Se) have been prepared by reaction of [(mu-RE)(mu-CO
)Fe-2(CO)(6)][Et-3-NH] with (mu-S-2)Fe-2(CO)(6). While these salts react in
situ with MeI to yield the double clusters [(mu-RE)Fe-2(CO)(6)]-(mu(4)-S)[
(mu-MeS)Fe-2(CO)(6)], their reactions with SO2Cl2 in the presence of excess
[(mu-RE) (mu-CO)Fe-2(CO)(6)][Et3NH] afford the triple clusters [(mu-RE)Fe-
2(CO)(6)](2)[(mu(4)-S)(Fe-2- (CO)(6))(2)(mu(4)-S)].