Relationship between the highest occupied Kohn-Sham orbital eigenvalue andionization energy

Recent arguments for and against the equivalence of the highest occupied or bital eigenvalue of the Kohn-Sham theory and ionization energy are discusse d. It is shown that for physically realistic systems with a nonintegral num ber of electrons, which are described by the thermal average of two systems , each with an integer number of electrons, an equivalent Kohn-Sham system exists. This is done by writing explicit expressions for the exchange-corre lation potential constructed to give the mixed-state density, and then rela ting it to the mixed-state exchange-correlation energy functional by employ ing the virial theorem sum rule of Levy and Perdew [phys. Rev. A 32, 2010 ( 1985)]. Further, the functional derivative of the mixed-state exchange-corr elation energy functional is obtained in terms of this potential. This is t hen used to show, without recourse to Janak's theorem [Phys. Rev. B 18, 716 5 (1978)], that epsilon(max)(N)=-I(Z), where Z is an integer and (Z-1) <N<Z . Thus the original arguments about the equivalence of the highest occupied Kohn-Sham orbital eigenenergy and the ionization energy which were based o n Janak's theorem are valid, and the two quantities are equal. [S0163-1829( 99)11131-7].