The process of brittle fracture in gallium arsenide was investigated to cla
rify the relation between the dynamics of crack propagation and the observe
d structure on the fracture surface with time-sensitive and structure-sensi
tive methods. Within the full range of length scales, i.e., spanning eight
orders of magnitude from angstrom units to centimeters, the fracture surfac
e was characterized with a manifold of structure-sensitive methods comprisi
ng optical microscopy, profilometry, atomic force microscopy, and scanning
tunneling microscopy. We found that it is possible to predict the local ato
mic-scale microstructure of a fracture surface from the knowledge of the gl
obal macrostructure. The investigation of the fracture kinetics showed that
the crack propagation process is characterized by three distinct velocity
ranges. The present experimental results on structure and kinetics are cons
istently interpreted within the framework of a nonlinear dynamic instabilit
y in crack propagation. [S0163-1829(99)07131-3].