The transition from complex-periodic to chaotic behavior is investigated in
oscillatory media supporting spiral waves. We find turbulent regimes chara
cterized by the spontaneous nucleation, proliferation, and erratic motion o
f synchronization defect lines which separate domains of different oscillat
ion phases. The line-defect dynamics is controlled by the competition betwe
en diffusion, which reduces line length and curvature, and phase-gradient-i
nduced growth. The onset of each type of defect-line turbulence is identifi
ed with a nonequilibrium phase transition characterized by nontrivial criti
cal exponents.