Coordination sites of ATP to Fe-III as evidenced by a H-1 and P-31 NMR relaxation study

Authors
Du, F Mao, XA Li, DF Liao, ZR
Citation
F. Du et al., Coordination sites of ATP to Fe-III as evidenced by a H-1 and P-31 NMR relaxation study, POLYHEDRON, 18(17), 1999, pp. 2327-2330
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
18
Issue
17
Year of publication
1999
Pages
2327 - 2330
Database
ISI
SICI code
0277-5387(1999)18:17<2327:CSOATF>2.0.ZU;2-7
Abstract
Relative interatomic distances between the NMR nuclei (H-1 and P-31) and th e ferric ion of the ATP-Fe-III complex in solution are evaluated by quantit ative analysis of the relaxation enhancements. The results show that, at pH 3, N-1 of the purine base is the coordination site rather than N-7. (C) 19 99 Elsevier Science Ltd. All rights reserved.