Surface modification of poly(tetrafluoroethylene) by plasma pretreatment and adsorption of polyelectrolytes

Citation
U. Lappan et al., Surface modification of poly(tetrafluoroethylene) by plasma pretreatment and adsorption of polyelectrolytes, POLYMER, 40(14), 1999, pp. 4087-4091
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER
ISSN journal
00323861 → ACNP
Volume
40
Issue
14
Year of publication
1999
Pages
4087 - 4091
Database
ISI
SICI code
0032-3861(199906)40:14<4087:SMOPBP>2.0.ZU;2-X
Abstract
The adsorption of polyelectrolytes onto plasma-pretreated poly(tetrafluoroe thylene) (PTFE) surfaces is reported as a method for fluoropolymer surface modification. PTFE was treated in oxygen or ammonia plasmas in order to int roduce oxygen-containing and nitrogen-containing groups, respectively, whic h increase the surface free energy and make possible the adsorption of poly electrolytes via electrostatic interactions. We investigated the adsorption of poly(diallyldimethylammonium chloride) and poly(sodium styrenesulfonate ) on the plasma-pretreated PTFE. The modification effects were evaluated by means of contact angle and streaming potential measurements. (C) 1999 Else vier Science Ltd. All rights reserved.