U. Lappan et al., Surface modification of poly(tetrafluoroethylene) by plasma pretreatment and adsorption of polyelectrolytes, POLYMER, 40(14), 1999, pp. 4087-4091
The adsorption of polyelectrolytes onto plasma-pretreated poly(tetrafluoroe
thylene) (PTFE) surfaces is reported as a method for fluoropolymer surface
modification. PTFE was treated in oxygen or ammonia plasmas in order to int
roduce oxygen-containing and nitrogen-containing groups, respectively, whic
h increase the surface free energy and make possible the adsorption of poly
electrolytes via electrostatic interactions. We investigated the adsorption
of poly(diallyldimethylammonium chloride) and poly(sodium styrenesulfonate
) on the plasma-pretreated PTFE. The modification effects were evaluated by
means of contact angle and streaming potential measurements. (C) 1999 Else
vier Science Ltd. All rights reserved.