In this work is reported a F center for the first time in a quaternary syst
em; mixture of four alkali halide salts, that give a crystalline material,
whith a trapped electron, The optical absorption spectra is obtained shown
a single F and K bands, that implies a definide lattice constant of the mat
erial and a single phase, that appears clearly in the X ray difractometry s
pectra. The Vegard's generalized law is extended, valid for a recently repo
rted novel ternary crystal. The constant lattice, obtained by F center Moll
wo-Ivey's law by X ray difractometry and the extended Vegard's generalized
law are in good agreement.