E. Tomasetti et al., Surface characterization of polypropylene/(ethylene-propylene) copolymer blends (PP/EP): Application to injection-moulded systems, SURF INT AN, 27(8), 1999, pp. 735-742
Polypropylene/ethylene - propylene copolymer blends (PP/EP) were characteri
zed by time-of-flight (ToF), SIMS, by dynamic wetting and by atomic force m
icroscopy and force modulation spectroscopy (AFM-FMM), In a first step, mod
el systems of compression-moulded PP/EP physical blends were prepared. With
these materials, ToF-SIMS provides linear relationships between the select
ed peak and the EP content in the material. This indicates that both phases
are present at the surface in the same concentrations as in the bulk. Howe
ver, the EP signal is weak. In dynamic wetting measurements with water, for
each tested blend composition the advancing contact angle corresponds to t
hat of PP and the receding contact angle corresponds to that of EP, This me
thod is thus suitable for detecting the presence of the two phases at the s
urface even for low concentrations of one consituent, The force modulation
image gives elastic contrasts between EP and PP and is thus able to reveal
the surface morphology, In a second step, these methods were used to charac
terize injection-moulded PP/EP reactor blends. Both AFM-FMM and ToF-SIMS su
ggest that a PP skin covers EP nodules at the surface. This is confirmed by
electron microscopy examinations of cross-sections. This surface phase seg
regation leads to the presence of PP in the first 100 mm of the surface and
could be explained by preferential wetting of the mould by the phase with
the lower viscosity, PP in this case. However, dynamic wetting reveals that
the PP skin is not complete. Thus, a low EP concentration may be found at
the surface, in the form either of EP nodules or of EP molecules having mig
rated through the PP skin, Copyright (C) 1999 John Wiley & Sons, Ltd.