Carbonate co-adsorption geometry on TiO2(110) 1 x 1-Na

Authors
Gutierrez-Sosa, A Walsh, JF Lindsay, R Wincott, PL Thornton, G
Citation
A. Gutierrez-sosa et al., Carbonate co-adsorption geometry on TiO2(110) 1 x 1-Na, SURF SCI, 435, 1999, pp. 538-542
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
SURFACE SCIENCE
ISSN journal
00396028 → ACNP
Volume
435
Year of publication
1999
Pages
538 - 542
Database
ISI
SICI code
0039-6028(19990802)435:<538:CCGOT1>2.0.ZU;2-K
Abstract
The influence of Na on the adsorption and reaction of CO2 with TiO2(110)1 x 1 has been studied using C K-edge NEXAFS. CO2 forms carbonate on the Na-co vered surface, the molecular plane being twisted 32+/-5 degrees out of the [001] azimuth with a tilt of 46+/-5 degrees away from the surface normal. ( C) 1999 Published by Elsevier Science B.V. All rights reserved.