alpha-keto esters as electrophiles for the Chalcogeno-Baylis-Hillman reaction

Citation
D. Basavaiah et al., alpha-keto esters as electrophiles for the Chalcogeno-Baylis-Hillman reaction, SYNLETT, (8), 1999, pp. 1249-1250
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
8
Year of publication
1999
Pages
1249 - 1250
Database
ISI
SICI code
0936-5214(199908):8<1249:AEAEFT>2.0.ZU;2-#
Abstract
The Baylis-Hillman reaction of alpha-keto esters with alpha,beta-unsaturate d ketones under the catalytic influence of dimethyl sulfide in the presence of titanium tetrachloride leading to the formation of 2-aryl-2-hydroxy-3-m ethylene-4-oxoalkanoates has been described.