A facile synthesis of 3-oxo-7 alpha H-eudesma-4-en-9 beta, 12-diol

Citation
Lj. Liu et al., A facile synthesis of 3-oxo-7 alpha H-eudesma-4-en-9 beta, 12-diol, SYN COMMUN, 29(19), 1999, pp. 3379-3384
Citations number
6
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
19
Year of publication
1999
Pages
3379 - 3384
Database
ISI
SICI code
0039-7911(1999)29:19<3379:AFSO3A>2.0.ZU;2-W
Abstract
A facile synthesis of a mixture of the C-11 isomeric 3-oxo-7 alpha H-eudesm a-4-en-9 beta.12-diol has been achieved from oxycarvone. The C-11 configura tion of natural product is established through comparison of H-1 NMR spectr a between synthetic 1b, or the mixture of 1a and 1b, and natural diol.