Allylation of aldehydes via Umpolung of pi-allylpalladium(II) with triethylborane

Authors
Kimura, M Kiyama, I Tomizawa, T Horino, Y Tanaka, S Tamaru, Y
Citation
M. Kimura et al., Allylation of aldehydes via Umpolung of pi-allylpalladium(II) with triethylborane, TETRAHEDR L, 40(37), 1999, pp. 6795-6798
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
37
Year of publication
1999
Pages
6795 - 6798
Database
ISI
SICI code
0040-4039(19990910)40:37<6795:AOAVUO>2.0.ZU;2-1
Abstract
Triethylborane induces allylic substrates (benzoates, phenyl ethers, benzyl ethers, but not halides) to undergo allylation of aldehydes in the presenc e of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) The rea ction proceeds via Umpolung of pi-allylpalladium. (C) 1999 Elsevier Science Ltd. All rights reserved.